Synthesis and Characteristics of CaCO3 from Kepah Clam Shells (Polymesoda erosa) as Anode Doping of Lithium-Ion Batteries

  • Yunior Trisakti Jurusan Fisika, Universitas Bangka Belitung
  • Lizia Miratsi Jurusan Fisika, Universitas Bangka Belitung
  • Widodo Budi Kurniawan Jurusan Fisika, Universitas Bangka Belitung

Abstract

Synthesis and Characteristics of CaCO3 from Kepah Clam Shells (Polymesoda erosa) as Anode Doping of Lithium-Ion Batteries

LTO (Lithium Titanate Oxide) or Li4Ti5O12 is one of the candidates for graphite replacement anode material in the production of Lithium-ion batteries. However, LTO materials have the disadvantage of low electrical conductivity, which limits the working level of the battery. Kepah clam shells are one of the wastes that have not been widely used even though the amount is still very abundant, and is expected to have the potential to be in the source of CaCO3 because it contains high amounts of calcium. Therefore, this study aims to determine the content of CaCO3 in the shell of the kepah clam (Polymesoda erosa) and determine the conductivity value of the LTO anode doped with CaCO3 of the kepah clam shell. The synthesis method used is the solid state reaction method with variations in doping concentrations of 0.00 mol, 0.10 mol, 0.15 mol, and 0.20 mol. The results of XRF analysis on the shell powder showed that the most dominant element content was Ca which was 97.63%. So it shows that calcium carbonate (CaCO3) from the shells of kepah mussels was successfully prepared. Furthermore, the anode active material was obtained, which if obtained XRD results and analyzed would show the absence of the CaCO3 phase, and there was no doping influence, then the active material powder was synthesized Li4Ti5O12 anode sheet doped CaCO3 shell. As for knowing the conductivity value of the Li4Ti5O12 anode sheet doped by CaCO3 clam shells, it is further characterized using Electrochemical Impedance Spectroscopy (EIS).

Keywords: Key words : Kepah clam shell, CaCO3 doping, and Li4Ti5O12.

Downloads

Download data is not yet available.

References

M. E. Saputra, "Pengaruh Doping CaCO3 Dari Cangkang Kerang Darah (Anadara granosa) Terhadap Struktur Kristal dan Nilai Konduktivitas Anoda Li4Ti5O12," Universitas Bangka Belitung, Bangka, 2021.

A. I. Najihah and Z. A. I. Supardi, "Pengaruh Waktu Tahan Kalsinasi Terhadap Performa Elektrokimia Anoda Li4Ti5O12," Jurnal Inovasi Fisika Indonesia (IFI) , vol. 8, no. 03, pp. 62-65, 2019.

A. Subhan, D. Setiawan and S. Saptari, "Preparation And Ionic Conductivity Of Li3,9Ca0,1Ti5O12 Using Waste Chicken Eggshells As Ca Source For Anode Material of Lithium-Ion Batteries," IOP Conf. Series: Materials Science and Enggineering, 2018.

F. Afriani, Mustari and Y. Tiandho, "Pengaruh Lama Pemanasan Terhadap Karakteristik Kristal Kalsium dari Limbah Cangkang Kerang," Jurnal EduMatSains, vol. 2, no. 2, pp. 189-200, 2018.

F. Akbar, R. Kusumaningrum, M. S. Jamit, A. Noviyanto, W. B. Widayatno, A. S. Wismogroho and N. T. Rochman, "Sintesis Ca2P2O7 dari Limbah Kerang dengan Metode Solvothermal," Jurnal Fisika Dan Aplikasinya, vol. 15, no. 3, pp. 111-113, 2019.

I. Sumarlan and R. B. Mentari, "Esterification of Waste Cooking Oil using Heterogeneous Catalyst from Pearl Shell," Jurnal Akademika Kimia , vol. 9, no. 3, pp. 183-190, 2020.

P. M. Insani S and Rahmatsyah, "Analisis Pola Struktur Kalsium Karbonat (CaCO3) pada Cangkang Kerang Darah (Anadara granosa) di Bukit Kerang Kabupaten Aceh Tamiang," Jurnal Teori dan Aplikasi Fisika, vol. 09, no. 01, pp. 23-32, 2021.

A. O. Maisyarah, A. Shofiyani and Rudiyansyah, "Sintesis CaO Dari Cangkang Kerang Ale-Ale (Meretrix meretrix) Pada Suhu Kalsinasi 900°C," Jurnal Kimia Khatulistiwa, vol. 8, no. 1, pp. 37-40, 2019.

Hariyati, A. Shofiyani and M. A. Wibowo, "Ekstraksi Kalsium Karbonat (CaCO3) DARI Bahan Dasar Cangkang Kerang Ale-Ale (Meretrix meretrix) Pada Temperatur KalsinasI 500°C," Jurnal Kimia Khatulistiwa, vol. 8, no. 1, pp. 54-58, 2019.

Ipi, "Sintesis Elektroda Anoda Baterai Ion Litium Berbasis Karbon Aktif Kulit Lada," Universitas Bangka Belitung, Bangka, 2021.

D. Fatahilah, " Pengaruh Variasi Doping Zirkonium Pada Lithium Sodium Titanium Oxide (Na2Li2Ti6ZrxO14) Terhadap Kinerjanya Sebagai Bahan Aktif Anoda Baterai Lithium-Ion," UNY, Yogyakarta, 2018.

Y. Tiandho, W. Sunanda, F. Afriani, A. Indriawati and T. Handayani, "Accurate model for temperature dependence of solar cell performance according to phonon energy," Latvian Journal of Physics and Technical Sciences, vol. 55, no. 5, pp. 15-25, 2018.

D. &. R. T. B. Linden, "Handbook Of Batteries E Ed. 3 Penyunt," The Mcgraw-Hills Companies, Inc, Amerika Serikat, 2002.

J. A. Khalil, "Sintesis Dan Karakterisasi Nanokomposit Fe3O4/Go/Cnts Sebagai Bahan Anoda Baterai Lithium," UNIMED, Medan, 2019.

A. Subhan, D. Setiawan, S. A. Saptari and B. Prihandoko, "Analisa Koefisien Difusi Anoda Lto Yang Didoping Ca Dari Limbah Kulit Telur Untuk Aplikasi Baterai Lithium-Ion Berdaya Tinggi," Jurnal Material dan Energi Indonesia, vol. 07, no. 02, pp. 6-11, 2017.

Published
2022-12-19
How to Cite
[1]
Y. Trisakti, L. Miratsi, and W. Kurniawan, “Synthesis and Characteristics of CaCO3 from Kepah Clam Shells (Polymesoda erosa) as Anode Doping of Lithium-Ion Batteries”, JRFI, vol. 3, no. 1, pp. 19-24, Dec. 2022.
Section
Articles
Abstract viewed = 527 times
PDF (Bahasa Indonesia) downloaded = 651 times