Adsorption Study of Carbon Chitosan Composite Beads from Ketapang Fruit Shell (Terminalia catappa L) on Methylene Blue Dyes
Kajian Adsorpsi Beads Komposit Kitosan Karbon Cangkang Buah Ketapang (Terminalia catappa L) Terhadap Zat Warna Metilen Biru
Keywords:
adsorption, kinetics, composite beads, methylene blue, ketapang fruit shells
Abstract
Carbon chitosan composite beads were synthesized using chitosan and activated carbon from Ketapang fruit shells (Terminalia catappa L) using PVA as a crosslinker. The adsorbent was synthesized with a chitosan: activated carbon ratio of 0.8 grams versus 0.2 grams. Material characterization using FTIR shows the presence of C-O, N-H, C-N, C=O, C-H, and -OH functional groups. Adsorption of carbon chitosan composite beads on methylene blue achieved maximum results at a contact time of 75 minutes using an adsorbent mass of 0.15 grams with an adsorption percentage reaching 97%. The adsorption kinetics follows a pseudo second order kinetic model with a k value of 1.3467 mg-s-.
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References
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Auta, M., & Hameed, B. H. (2013). Coalesced chitosan activated carbon composite for batch and fixed-bed adsorption of cationic and anionic dyes. Colloids and Surfaces B: Biointerfaces, 105(2010), 199–206. https://doi.org/10.1016/j.colsurfb.2012.12.021
Fatombi, J. K., Idohou, E. A., Osseni, S. A., Agani, I., Neumeyer, D., Verelst, M., Mauricot, R., & Aminou, T. (2019). Adsorption of Indigo Carmine from Aqueous Solution by Chitosan and Chitosan/Activated Carbon Composite: Kinetics, Isotherms and Thermodynamics Studies. Fibers and Polymers, 20(9), 1820–1832. https://doi.org/10.1007/s12221-019-1107-y
Idohou, E. A., Fatombi, J. K., Osseni, S. A., Agani, I., Neumeyer, D., Verelst, M., Mauricot, R., & Aminou, T. (2020). Preparation of activated carbon/chitosan/Carica papaya seeds composite for efficient adsorption of cationic dye from aqueous solution. Surfaces and Interfaces, 21(September), 100741. https://doi.org/10.1016/j.surfin.2020.100741
Keshvardoostchokami, M., Majidi, M., Zamani, A., & Liu, B. (2021). A review on the use of chitosan and chitosan derivatives as the bio-adsorbents for the water treatment: Removal of nitrogen-containing pollutants. Carbohydrate Polymers, 273(September), 118625. https://doi.org/10.1016/j.carbpol.2021.118625
Nisa, N. N., & Cahyanto, A. D. (2023). Isotherm Study, Adsorption Kinetics and Thermodynamics of Lead Using Combination Adsorbent of Chitosan and Coffee Ground Activated Carbon. Jurnal Riset Teknologi Pencegahan Pencemaran Industri, 14(3), 1–11. https://doi.org/10.21771/jrtppi.2023.v14.no3.p1-11
Nowruzi, R., Heydari, M., & Javanbakht, V. (2020). Synthesis of a chitosan/polyvinyl alcohol/activate carbon biocomposite for removal of hexavalent chromium from aqueous solution. International Journal of Biological Macromolecules, 147, 209–216. https://doi.org/10.1016/j.ijbiomac.2020.01.044
Nurhidayanti, N., & Riyadi, A. (2024). Adsorption, Kinetic and Thermodynamic Studies for the Adsorption of Cadmium onto Combination of Chitosan and Coffee Ground Activated Carbon. Rekayasa, 17(1), 1–9. https://doi.org/10.21107/rekayasa.v17i1.20364
Purnaningtyas, M. A. K., Sudiono, S., & Siswanta, D. (2020). Synthesis of activated carbon/chitosan/alginate beads powder as an adsorbent for methylene blue and methyl violet 2b dyes. Indonesian Journal of Chemistry, 20(5), 1119–1130. https://doi.org/10.22146/ijc.49026
Suwazan, D., & Nurhidayanti, N. (2022). Efektivitas Kombinasi Kitosan dan Ampas Teh Sebagai Adsorben Alami dalam Menurunkan Konsentrasi Timbal Pada Limbah Cair PT PXI. Jurnal Ilmu Lingkungan, 20(1), 37–44. https://doi.org/10.14710/jil.20.1.37-44
Triawan, D. A., Nesbah, N., Fitriani, D., Kimia, J., Matematika, F., Pengetahuan, I., & Universitas Bengkulu, A. (2017). Crude Palm Oil’s (CPO) Fly Ash As A Low-Cost Adsorben For Removal of Methylen Blue (MB) From Aqueous Solution. Jurnal Kimia Riset, 2(1), 10–15.
Triawan, D. A., Nurwidiyani, R., Nesbah, Hamurwani, D. S., Puteri, N. A., Nasution, A. V., & Yuliyani, U. (2023). Preparation of Liquid Smoke Made from Coffee Husk and Its Application as A Latex Coagulant. Jurnal Teknologi Pertanian, 24(1), 1–8.
Zahro, S. F., & Adityosulindro, S. (2023). Literature Review: Penggunaan Bahan Berbasis Limbah Sebagai Adsorben untuk Degradasi Zat Warna pada Air Limbah. Jurnal Kesehatan Lingkungan Indonesia, 22(3), 359–368. https://doi.org/10.14710/jkli.22.3.359-368
Published
2024-10-31
How to Cite
Nurwidiyani, R., Sigiro, C., Putranto, A., & Triawan, D. (2024). Adsorption Study of Carbon Chitosan Composite Beads from Ketapang Fruit Shell (Terminalia catappa L) on Methylene Blue Dyes. Stannum : Jurnal Sains Dan Terapan Kimia, 6(2), 115-121. https://doi.org/10.33019/jstk.v6i2.5631
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Articles
Copyright (c) 2024 Ria Nurwidiyani, Chelin Dion Sigiro, Agus Martono Hadi Putranto, Deni Agus Triawan
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